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    <pre style="white-space:pre-line"><code>Makale / Article

baÄŸa sahiptir ve polimerizasyon iÃ§in bir Ã§apraz baÄŸ-        because dialkyl phosphate has two double bonds and
layÄ±cÄ±dÄ±r. Solvay, yÃ¼ksek MAP / DAP oranÄ±, dÃ¼ÅŸÃ¼k asit       is a crosslinker for polymerization. Solvay has devel-
iÃ§eriÄŸi ve yaygÄ±n olarak kullanÄ±lan monomer kompo-          oped a proprietary technology that makes possible to
zisyonlarÄ± veya solventler ile iyi uyumluluk gÃ¶steren       produce phosphate monomers with high MAP/DAP
fosfat monomerler Ã¼retmeyi mÃ¼mkÃ¼n kÄ±lan Ã¶zel bir            ratio, low acid content, and good compatibility with
teknoloji geliÅŸtirmiÅŸtir.                                   commonly used monomer compositions or solvents. In
Solvayâ€™Ä±n Ã¶zel fosfat ester monomerleri ve sÃ¼rfaktan-       addition to phosphate ester monomers, Solvay offers
larÄ±, polimer dispersiyonuna spesifik iÅŸlevsellik katmak    a range of phosphate ester surfactants which can be
amacÄ±yla geliÅŸtirilmiÅŸtir. Bu yazÄ±da, su direncinde, me-    used in emulsion polymerization and coatings formu-
tal yapÄ±ÅŸmasÄ±nda ve korozyon direncinde yapÄ±lan iyi-        lations.
leÅŸtirmelere kadar Ã§eÅŸitli avantajlarÄ±n yanÄ± sÄ±ra spesifik  Solvayâ€™s specialty phosphate ester monomers and sur-
Ã¶rneklerin bir Ã¶zeti deÄŸerlendirilmiÅŸtir.                   factants have been developed to enable specific func-
Fosfat Ester Monomerlerin EmÃ¼lsiyon                         tionality to be built into the polymer dispersion. In this
Polimerizasyonunda KullanÄ±mÄ±                                paper, we presented an overview of the benefits as
Bir kaplamanÄ±n hem kuru hem de Ä±slak koÅŸullar altÄ±n-        well as specific examples ranging from improvements
da farklÄ± yÃ¼zeylere yapÄ±ÅŸabilme Ã¶zelliÄŸi birÃ§ok uygula-     in water resistance, metal adhe-sion and corrosion re-
ma iÃ§in kritik Ã¶nem taÅŸÄ±r. YapÄ±ÅŸmayÄ± geliÅŸtirmenin bir      sistance.
yÃ¶ntemi reÃ§inelere yapÄ±ÅŸmayÄ± teÅŸvik eden fonksiyonel        Phosphate Ester Monomers in Emulsion
gruplarÄ± dahil etmektir. Bu iÅŸlevsel gruplar, substratlar   Polymerization
ile spesifik etkileÅŸimlere girerler ve bÃ¶ylece yapÄ±ÅŸmayÄ±    The ability of a coating to adhere onto different sub-
geliÅŸtirirler. Bu makalede, fosfat ester monomerlerin,      strates under both dry and wet conditions is critical for
emÃ¼lsiyon polimerizasyonu ile sentezlenen polimer-          many applications. One method of improving adhe-
lerdeki uygulamalarÄ± gÃ¶rÃ¼lebilir. Bu polimerler kap-        sion is to incorporate functional groups that promote
lamalarÄ±n metal yÃ¼zeylere yapÄ±ÅŸmasÄ±nÄ± iyileÅŸtirmek          adhesion into the resins. These functional groups en-
iÃ§in tasarlanmÄ±ÅŸtÄ±r. Fosfat ester monomerler, bÃ¼yÃ¼k         gage in specific interactions with the substrates, and,
formÃ¼lasyon veya prosedÃ¼r deÄŸiÅŸikliÄŸi olmaksÄ±zÄ±n po-        thus, improve the adhesion. Herein, we describe ap-
limer reÃ§inelerine sorunsuz bir ÅŸekilde dahil edilmiÅŸtir.   plications of phosphate ester monomers in polymers
Bu monomerler, Ã§eÅŸitli yÃ¼zeylerde bulunan Ã¶zellikle-        synthesized by emulsion polymerization. These poly-
rin iyileÅŸtirilmesi iÃ§in geniÅŸ bir uygulama yelpazesinde    mers are designed to improve the adhesion of coat-
kullanÄ±lmÄ±ÅŸtÄ±r. FormÃ¼le edilmiÅŸ kaplamalar iÃ§in yapÄ±ÅŸ-      ings and adhesives on metal surfaces. Phosphate ester
ma ve korozyon direnci gibi diÄŸer ilgili Ã¶zellikleri ise    monomers were incorporated smoothly into the poly-
dikkat Ã§ekici ÅŸekilde iyileÅŸtirilmiÅŸtir.                    mer resins without major formulation or procedure
Sipomer PAM 600                                             change. These monomers have been used in a wide
Sipomer PAM 600, metal, beton, cam Ã¼zerine yapÄ±ÅŸ-           range of applications to improve the properties on a
mayÄ± arttÄ±ran ve korozyon direncini arttÄ±ran yeni geliÅŸ-    variety of substrates. They dramatically improved ad-
tirilmiÅŸ Ã¶zel monomer taÅŸÄ±yan fonksiyonel gruplardÄ±r.       hesion as well as other related properties, such as cor-
Bu Ã§alÄ±ÅŸmada, saf akrilik reÃ§ine, emÃ¼lsiyon polimeri-       rosion resistance, for the formulated coatings.
zasyonu ile sentezlendi ve Sipomer PAM 600 0-4 phm          Sipomer PAM 600
seviyesinde birleÅŸtirildi. Tablo 1, oluÅŸan lateks Ã¶zellik-  Sipomer PAM 600 is a newly developed specialty
lerini listelemektedir. Sipomer PAM 600â€™Ã¼n dahil edil-      monomer bearing functional groups which enhance
mesinin, dÃ¶nÃ¼ÅŸtÃ¼rmeyi etkilemediÄŸini ve iyi dengenin        adhesion to metal, concrete, glass and improves cor-
sergilendiÄŸi lateks ile sonuÃ§landÄ±ÄŸÄ± gÃ¶rÃ¼lebilir. KarÅŸÄ±-    rosion resistance. A full acrylic resin was synthesized
laÅŸtÄ±rma iÃ§in Sipomer PAM 600 iÃ§ermeyen reÃ§ineler           by emulsion polymerization and Sipomer PAM 600
sentezlenmiÅŸtir.                                            was incorporated at a level of 0-4 phm. Table 1 lists
                                                            the resulting latex properties. It should be emphasized
                                                            that the incorporation of Sipomer PAM 600 did not af-
                                                            fect the conversion and resulted in latex that exhibited
                                                            good stability. Resins without Sipomer PAM 600 were
                                                            synthesized for comparison proposes.

                                                            Turkcoat                                                    23</code></pre>
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